No. Once a goalkeeper establishes control of the ball, no opposing player may interfere with goalkeepers ability to release the ball back into play. Bouncing the ball and catching prior to kicking or throwing is not considered release it into play. However, if the keeper loses control of the ball, it may be played by any player.
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Yes you can. Obviously you just have to make sure that the ball gets around the goalie and into the goals to give you a score. As well as making sure you shoot from inside the circle.