In MLB, the career leader for innings pitched is Cy Young who pitched 7354 innings in a career that spanned 1890-1911. As far as the 'modern' innings pitched leader, that would be Phil Niekro who pitched 5404 innings in a career that spanned 1964-1987.
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As of the 2008 season, that would be Derek Jeter of the New York Yankees with 123 playoff games. Bernie Williams, formerly of the Yankees, is second with 121.
In MLB, Jesse Orosco with 1252.
The current (June 30, 2009) pitcher with the most games is Trevor Hoffman with 953.
No surprise (to me at least) that the answer is Whitey Ford, who started 22 World Series games, winning ten of them -- also a record.