Back in ancient times before the game really formed rules they would use a human head as a ball. there would be 5 people on each team trying to score at a goal on each side of a feild. if your team lost then you would be kill and your head would be used as a ball.
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Waterproofed leather or plastic. Most balls are stitched, but the really high quality ones are "thermally bonded" using a machine.
They use different kinds of soccer balls...if you mean what shape then it's spherical with pentagon or hexagonal shapes all over the sphere