There are:
Two outside hitters (or, "lefts")
Two middle blockers, but only one is on the court at a time
One libero (who usually plays back row for the middles)
One or two setters (if there is one setter: a right front plays when the setter is back row and a right back (usually a defensive specialist) plays when the setter is front row)
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You'll these have people in the front: setter, center, and power on leftside. Depending on the rotation you can have a weak side hitter on the right
The back row depends on how you set up your team strategy and what the other team is doing. There are a lot of ways to put everyone so it can change what they're name is. Generally they're called back right, back middle, back left or whatever.
Some people call them ds or defensive specialists, but that's a job not a position.
And there's the libero, but they play only play back row and don't have to sign in to rotate. They wear a cool jersey.
the six positions are setter, middle, power, and the three back rows (which are the same name but in back row)
Setter, Middle, Offside (tech), power, libero, server, and i guess a passer? Back row and front row have the same names (power, setter, Middle)