There have been countless. The most recent was Mike Mussina in 2008. Roger Clemens was the only pitcher ever win 20 out of twenty-one decisions. Jack Chesbero holds the record for wins in a season with 41. These are just a few examples.
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Ty cobb
The fewest wins in an NBA season is 9 by the 1972-73 Philadelphia 76ers. Their record that year was 9-73.
Colts
Fewest walks in a season is kind of a bad question because I'm sure there have been plenty of players who could have played 20 games and had zero walks in any given year (or something like that). However, the MLB record for fewest walks while still being eligible for the batting title was Shawon Dunston who had 8 in 490 at-bats in 1997.
No. Babe had 97 wins as a pitcher ... 94 in the regular season and 3 in the World Series. No MLB player has 100 HRs and 100 wins as a pitcher.