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In MLB, for pitchers that threw at least 162 innings in a season, that would be Dutch Leonard who had an ERA of 0.96 for the Boston Red Sox in the 1914 season. Leonard pitched 224 2/3 innings and gave up 24 earned runs. For pitchers that threw at least 100 innings in a season it is Tim Keefe who had an ERA of 0.86 for the Troy Trojans in 1880. Keefe pitched 105 innings and gave up 10 earned runs.

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