okay submissions are different depending on if your going against a CPU or Human,
For CPU: make sure they are fully drained (gassed) and if your going for a Knee Bar then kick the leg you are going to Knee Bar . other than that it is really hard to submit the CPU just try and get the Stamina Advantage and keep on trying to submit them
For Human: very simple, just wait till they are completely or almost drained (gassed) and Tap A rapidly to submit them (do same for CPU).
That's about it
The Rear Naked Choke is the most powerful
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clearly you can go to YouTube.... and search armbar,legbar, ect. but if you mean the video game its click the left trigger
Actually you click the right joystick.........