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There aren't any single moves that will put a king in checkmate instantly, obviously, but there are a few ways to checkmate a king quickly.

The Fool's Mate, which is done in two moves, goes:

  1. f3 e5
  2. g4 Qh4#

There are a few variations on this move.

The Scholar's Mate is more likely to happen (i.e. the opponent isn't an outright idiot) and happens quite often among beginning Chess players. It occurs in four moves:

  1. e4 e5
  2. Qh5 Nc6
  3. Bc4 Nf6?
  4. Qxf7#

You can look these two up on Wikipedia for more information.

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Q: Are there any moves to start with in a game of chess that will have opponent's king in checkmate right away?
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