2012.
The Washington Nationals made the playoffs in 2012 with the best record in MLB that season(98-64). They lost the NLCS to the St. Louis Cardinals 3 games to 2
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never because they were the Montreal Expos but funds got cut from the team and the players split up then the nationals took their spot.
After the 2007 season, the Washington Redskins were defeated in the wild-card round by the Seattle Seahawks, 35-14.
The last time the Redskins made it to the playoffs was in 2007. They lost the Wildcard game to the Seattle Seahawks
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The Nationals/Expos, who joined the NL in the 1969 expansion, have never appeared in the WS.