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Dundee United of Scotland, beat Barcelona home and away in the early days of the European Cup.
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Arsenal did it on February 16 2011. It was 2-1 in the champions league 1st leg at the Emirates. David Villa scored at 26 six minutes. 1-0 to Barcelona at half time. Van Persie scored a tight goal squeezing it past Victor Valdes at the 78th minute. 5 minutes later Arshavin curled one past Valdes which left him helpless.
Sadly at the second leg which was held at the nou camp saw Robin Van Persie get 2 yellow cards for kicking the ball away. Arsenal lost 3-1 at the second leg. Messi scored 1 at half time. Nasri took a corner and Sergio Busquets headed in a own-goal which held arsenal 3-2 on aggregate. Xavi took a shot in the box which took a tiny deflection of Sagna which got past Almunia. Koscielny barged messi in the penalty box which Barcelona got awarded a penalty. Lionel Messi calmly shot into the bottom-right corner which saw Messi score his second of the night.