Chuck Churn was the relief pitcher for the LA Dodgers in Game six of the 1959 World Series.
Second answer based on a Baseball card names Larry Sherry as brilliant in relief in Game 6.
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Derek Lowe was the winning pitcher in game 4 of the 2004 World Series.
Boston Red Sox pitcher, John Lackey, was the losing pitcher in Game 2 of the 2013 World Series.
The New York Yankees of the American League and the New York Mets of the National League were the 2 Major League Baseball teams that played in the World Series in the year 2000. The New York Yankees won the World Series in 5 games, the only game in which they lost was in Game 3 in which the Final Score was 4-2 and was played in Shea Stadium. Orlando Hernandez, a Starting Pitcher was given the Loss while John Franco, a Relief Pitcher was awarded the Win. In Game 5, the Yankees' Winning Pitcher was Mike Stanton, a Relief Pitcher and the Mets' Starting Pitcher, Al Leiter was awarded the Loss.
Randy Johnson in the 2001 World Series
Romero's 2 wins in relief for the Phillies in the 2008 World Series tied a record. Along with Romero, Mike Stanton of the 2000 New York Yankees, Duane Ward of the 1992 Toronto Blue Jays, Rawly Eastwick of the 1975 Cincinnati Reds, Ross Grimsley of the 1972 Cincinnati Reds, Larry Sherry of the 1959 Los Angeles Dodgers, Hugh Casey of the 1947 Brooklyn Dodgers, and Jesse Barnes of the 1921 New York Giants each had 2 relief wins in a single World Series.