History has not recorded that information although it is known that a team in the 1860s called the Brooklyn Excelsiors wore caps that looked somewhat like today's caps in that they had a rounded top. There were no rules back then that stated players had to wear a cap so most did not wear one although some players would wear a straw hat with a large brim to shade their face from the sun.
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It was invented in 1378 in the Byzantine Empire by E-Money
The baseball cap was originally invented in Europe somewhere in the west. The first baseball caps had a strap of cow hide to keep them on. It is thought that they were first made in the 1890's.
The first modern bottle cap was a screw-on cap invented in 1856. There was also a recloseable wire-and-cap type of bottle cap invented in the same year, still used today on some high-end beers such as Grolsch. The modern "crown cap" bottle cap was invented in 1890, modernized to the "pilfer proof" cap in 1936, and twist-off bottle caps in 1966. Bottle caps are no longer manufactured today, as most people drink their beer straight from their high-speed internet connection. :)
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Thomas Edison