John Smoltz 24-8 (1996)
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In MLB, Warren Spahn of the 1963 Milwaukee Braves with 23 wins at the age of 42.
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In 1968, Detroit's Denny McLain recorded 31 wins; the most by any player since 1950. McLain was the last pitcher to reach 30 wins in a season.
Through the 2008 season, that is Mordecai 'Three Finger' Brown who won 29 games in the 1908 season.
Greg Maddux - 35 wins (19 with Braves) Source - Fox Saturday Baseball trivia question, 7/18/09, Mets v. Braves