The most noted first pitch in the 2001 World Series was in game three when President George Bush threw out the first pitch.
The ceremonial first pitch was by President Bush. The first pitch of the game was by Curt Schilling.
The first baseball playoff to be called a "World Series" was the 1903 series between the Boston Red Sox and the Pittsburgh Pirates. In the first game, the starting pitchers were Deacon Phillipe and Cy Young. Since the Red Sox were the home team, and the visiting team bats first, Cy Young would have been the first person to throw a pitch in a game that would be considered part of a World Series.
The ceremonial first pitches before Game 1 of the World Series were performed by Hall of Famers Monte Irvin, Orlando Cepeda, Willie McCovey, Juan Marichal and Gaylord Perry. The starting first pitch was thrown by Tim Lincecum of the San Francisco Giants.
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In 1967 when Ken Brett pitched for the Boston Red Sox, he became the first teenager (19 years old ) to pitch in a World Series game. Going back a number of years, the first teenage position player to appear in a World Series was Fred Lindstrom in the 1924 World Series.