The champions league is a European club football (soccer) competition organized by the UEFA. It was formerly known as the European Champions Clubs' Cup and the European Cup.
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Everton were the Football League Champions in 1891.
Sunderland were the Football League Champions in 1902.
Derby County were the Football League Champions in 1972.
Arsenal were the Football League Champions in 1934.
Portsmouth were the Football League Champions in 1949.
Real Madrid won the Champions League in 2000. It was their 8th Champions League win.
Portsmouth were the Football League Champions in 1950.
Liverpool were the Football League Champions in 1990.
This is not possible as the winners of the Champions League and Europa League get direct entry to the next UEFA Champions League. Hence this case can't happen in the Champions League.
Champions league, of course.
Aston Villa were the Football League Champions in 1918.