Champions League games are played on Tuesdays and Wednesdays. The final used to be on a Wednesday, but it is now on a Saturday. In 2014 it is on Saturday the 24th of May.
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Everton were the Football League Champions in 1891.
Sunderland were the Football League Champions in 1902.
Derby County were the Football League Champions in 1972.
Arsenal were the Football League Champions in 1934.
THe last game of the 2012 Champions league is on 27th May, 2012. The final between Bayern and Chelsea will be played that day.
Portsmouth were the Football League Champions in 1949.
Real Madrid won the Champions League in 2000. It was their 8th Champions League win.
Portsmouth were the Football League Champions in 1950.
Liverpool were the Football League Champions in 1990.
This is not possible as the winners of the Champions League and Europa League get direct entry to the next UEFA Champions League. Hence this case can't happen in the Champions League.
Champions league, of course.