In terms of ability to fight, the answer is most likely Enricco Ciccone. In his first stint with the Caps he played 46 games and accumulated 174 PIMs. In his second term with the club, he had 103 PIMs in 43 games.
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Defenitely Alex Ovechkin, who is also the best player in the league. Comig after him are Mike Green, Niclkas Backstrom and Alexander Semin