I believe a batting average of 99.94 would be impossible as a batting average is determined by dividing the number of hits by the number of at bats. A hit in every at bat would be a batting average of 1.000. Any time at bat that would not result in a hit would be an average of less than that and reported as .xxx, thus it would not be possible to have an average of anything other than 1.000 or something in the .xxx area.
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if you number 99 i think it was Ronaldo Luis Nazário de Lima when he was with a.c milan