Starting at 1920, that is Jim Bagby of the Cleveland Indians in 1920, Lefty Grove of the Philadelphia Athletics in 1931, and Denny McLain of the Detroit Tigers in 1968 with 31.
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Between 1995-2009, that is Randy Johnson of the 2002 Arizona Diamondbacks and John Smoltz of the 1996 Atlanta Braves, both with 24.