The Major League Baseball Players who wear Number 20 as their Number on their Team Uniforms are Greg Norton of the Arizona Diamondbacks, Kevin Youkilis of the Boston Red Sox, Carlos Quentin of the Chicago White Sox, David Dellucci of the Cleveland Indians, Chris Iannetta of the Colorado Rockies, Juan Rivera of the Los Angeles Angels, Matt Tolbert of the Minnesota Twins, Steve Holm of the San Francisco Giants, Denny Stark of the Seattle Mariners, Brandon McCarthy of the Texas Rangers and Rod Barajas of the Toronto Blue Jays, and also Jorge Posada of the New York Yankees.
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Frank Robinson wore number 20 for the Baltimore Orioles.
Updated answer: Here are players that have had their #20 retired by their respected teams.
Lou BrockCardinals
Frank RobinsonOrioles and Reds
Pie TraynorPirates
Mike SchmidtPhillies
Don SuttonDodgers
Frank WhiteRoyals