As of October 2008
Theo Walcott - Arsenal
Jermain Defoe - Portsmouth
Xabi Alonso - Liverpool
Charles N'Zogbia - Newcastle
Jo - Manchester City
Stephen Moyse - FTYFCu12
UNASSIGNED - Man United
UNASSIGNED - Chelsea
For reference, it was also worn by
Johan Cruyff - Ajax
Thierry Henry - Arsenal & Barcelona
Guti - Real Madrid
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Two famous players come to mind who have worn the number 14 shirt. The great Johan Cruyff of Holland and Thierry Henry