You normally look at if they have a DH or not. The DH, or designated hitter, is meant as a replacement hitter for your pitcher. These are normally your aging players who still have some power. If the team normally has a DH, then it is American League. If the team does not usually have a DH, then it is National League.
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The only really stand-out difference between the two is that in the National League, the pitchers bat, and in the American League, the pitchers do not bat, and instead there is a Designated Hitter to take their place in the lineup.
they line up all the men naked in a row, then Elton John comes along and rates them on their bodies from 1-10. the man rated the highest gets to pick first.