I'm not quite sure if you mean teach Cheerleading or if you mean to take a class yourself...
Usually to take a cheerleading class the youngest age is usually 3 years old. To teach a cheerleading class I'm not sure, it usually depends on the gym/studio that you want to teach at.
Sorry, hope that helped a little(:
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If you mean allstar cheerleading which is a competitive sport, There are kids ages 4-18 doing it. When you get into college you can still cheer in college