The Chicago Cubs won five division titles in their history.
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As of the start of the 2007 season, the Cubs have won the National League pennant 16 times:
1945, 1938, 1935, 1932, 1929, 1918, 1910, 1908, 1907, 1906, 1886, 1885, 1882, 1881, 1880, and 1876
The Brewers have never won the National League pennant. When the Brewers were playing in the American League they won the pennant once, that being in 1982. They lost the World Series to the St. Louis Cardinals, 4 games to 3.
The Cubs are in the National League so they would not play in the ALCS, they would play in the NLCS. The Cubs have never won the NLCS.