Based on the stats
Overall 38 29 4 5
Home 19 16 1 2
Away 19 13 3 3
Real Madrid Matches Win Draw Lose
Overall 38 28 6 4
Home 19 16 1 2
Away 19 12 5 2
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Well,If you are talking about present so i would Say Fc Barcelona,But if you compare them with Their History as well,so real Madrid because it holds many much la liga's and champions league than Barcelona,But Barcelona at the present is much better than Real madrid because of their strongest line-up.
plus,Barcelona's players' have perfect chemistry because most of them were trained by barcelona,so most of them are playing with each other since their childhood.
yes the only reason they lost wuz bcuz of Cristiano Ronaldo and him getting injured every time he touched the ball