NCAA = National Collegiate Athletic Association, which is a college association made up of college teams and players who do not get paid, but usually play for a free scholarship MLB = Major League Baseball, which is a professional association made up of professional teams and paid players
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One other thing that makes it different is that you hit a ball with a bat and catch it with a glove.
An MLB Baseball is different from an ordinary baseball because MLB Baseballs are approved as a useful baseball by Major League Baseball officials themselves.