Jimmy Sebring of the Pittsburgh Pirates in the 7th inning of the first ever World Series game played October 1, 1903 between the Pirates and Boston Americans (now Red Sox).
The pitcher that gave up the home run was Cy Young and it was an inside the park homer.
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Larry Doby, of Paterson, New Jersey, was the 1st Black player to hit a home run in the World Series when he hit one on October 9, 1948.
Jim Bagby of the Cleveland Indians in the 4th inning of Game 5 of the 1920 World Series against the Brooklyn Dodgers.
Dan Driessen of the Cincinnati Reds in 4th inning of Game 3 of the 1976 World Series against the New York Yankees.
Jim Bagby of the Cleveland Indians in Game 5 of the 1920 World Series against the Brooklyn Dodgers (aka Robins).