It's best to read his biography.
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Charles Didelot
Fanny Bias was the first "recorded" ballerina to wear pointe shoes in Charles-Louis Didelot's ballet titled Flore et Zephire. Marie Taglioni then went on to make pointe a norm for all ballerinas. Her ballet shoes were flat shoes with a leather pointed toe. Anna Pavlova didn't actually invent the pointe shoe but she did add the leather sole to it to support her high arch. She is credited for making what is most similar to today's modern pointe shoe. I think at one time of her life she wore Capezios... not sure though.
Charles Didelot invented the first ballet shoes in the late 1700s.
the pointe shoe was invented in 1820 by Charles digelot
"En pointe" refers to dancing in pointe shoes. Non-pointe ballet shoes are demi-pointe shoes, and the dancing is "en demi-pointe".