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An accurate way to measure the air in a football is to measure the air pressure in the football. Then, using Boyle's Law, P(1) x V(1) = P(2) x V(2), you can compute the volume of air, at standard pressure. This will give you a quite accurate answer, since temperature really doesn't change things here. Note that, according to Boyle's Law, the higher the pressure in the football, the more air there is inside. This coincides with what you'd expect.

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