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In the end of the book series, Nate chooses Blair, and she is overjoyed while Serena is heartbroken. Even Gossip Girl said that Nate and Blair belong together. However, in the show, Blair ends up with Chuck, who is just a minor character in the books.
Shove It" by Santogold.
Jenny & Eric Dan & Serena Eric & Serena Dan & Eric
They get married in season 6, episode 10, which is the final episode.
In season 3, episode 13, Serena and Nate officially begin a relationship. Prior to this, Serena is involved with Nate's married cousin, Tripp, and after a car crash involving the two, Serena is hospitalized. Nate stays with her in the hospital, proving his affection for her. Their relationship is constantly challenged by Serena's efforts to find her father and Jenny's feelings for Nate. They separate at the end of the season because of a photo of Serena and ex-boyfriend Dan posted by Gossip Girl.