Prince Georgy Lvov was the first leader of Russia after the fall of the Czar. He headed the Provisional Government for the first 3 months of its existence immediately after Czar Nicholas II abdicated.
Later, Alexander Kerensky took over the Provisional Government for the next 3 months. Then Vladimir Lenin and the Bolsheviks overthrew the Provisional Government and Lenin became the leader.
In any event the very first leader of Russia "after the fall of Czarist Russia" was Prince Georgy Lvov and the Provisional Government.
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