The smell of the inside of a ping pong ball is most similar to Vick's Vaporub. During the production process, chemicals are used in production that cause the interior lining to develop a strong chemical smell. It can be a fun party trick to show your friends. For instance, in the middle of beer pong, you can break open the ball everyone was using and say, "hey guys, smell this!"
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Table Tennis balls are made of a type of plastic called celluloid. The odor in the ball is a by-product once the ball becomes cracked and the inside is exposed to air.