Brownian motion is the random movement of particles in a fluid due to collisions with molecules of the surrounding medium, such as air or water. A ping-pong ball suspended with a string is too large in comparison to the particles in the surrounding medium. The motion of such a macroscopic object is dominated by its interaction with the string and the macroscopic forces acting on it, making Brownian motion at that scale negligible and difficult to observe.
Brownian motion occurs in colloids due to the random collisions between the larger particles (colloidal particles) and the smaller, fast-moving molecules of the dispersing medium (such as water or air). In a colloid, the particles are small enough to be affected by these collisions, but large enough to be seen under a microscope. In contrast, in solutions or pure substances, the particles are either too small (like solute molecules) or too large (like bulk materials) to exhibit noticeable Brownian motion. Therefore, Brownian motion is a unique characteristic of colloidal systems where the balance between particle size and medium interaction is just right.
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This type of mixture is called a colloidal suspension. The particles in a colloidal suspension are larger than those in a solution, making them scatter light and giving the mixture a cloudy appearance. Despite being suspended, the particles do not settle out due to Brownian motion keeping them dispersed throughout the medium.
A drunk leaves the pub. There is an exactly 50:50 probability that he will lurch to the left or to the right. On planting his feet, there is again the same probability that he will lurch one way or the other. This is a classic example of a random walk. It's duplicated in lots of other random patterns, like Brownian Motion, where a pollen grain is pushed about by random collisions with water molecules, themselves undergoing random motion. Put simply, the outcome or destination of a random movement cannot be predicted accurately, except with a large number of determinations treated statistically.
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Particles that remain suspended in a fluid for some time before settling are referred to as "colloids." In a colloidal suspension, the particles are small enough to stay dispersed due to Brownian motion but large enough to eventually settle out of the fluid if left undisturbed. This phenomenon can be observed in various mixtures, such as milk or muddy water.
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