I think it was Travis Lee. -----
Jay Bell was the first player signed and the second was Matt Williams. Travis Lee did hit the first home run in Diamondbacks history, though, on March 31, 1998.
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In 2010, the Yankees played a three game interleague series in Arizona from June 21-23.
Brent Mayne played in just one game at first base for the Arizona Diamondbacks in 2004 and did not start. He played for a total of 5 outs, equivalent to .19 9-inning games. He made 2 putouts, had no assists, and committed no errors, equivalent to 0 errors per 9-inning game. He had no double plays.
Chris Snyder played in just one game at first base for the Arizona Diamondbacks in 2009 and did not start. He played for a total of 12 outs, equivalent to .44 9-inning games. He made one putout, had no assists, and committed no errors, equivalent to 0 errors per 9-inning game. He had no double plays.
Jeff Cirillo played in 2 games at first base for the Arizona Diamondbacks in 2007, starting in none of them. He played for a total of 9 outs, equivalent to .33 9-inning games. He made one putout, had one assist, and committed no errors, equivalent to 0 errors per 9-inning game. He had no double plays.
As of September 2021, the player with the most career hits against the San Diego Padres is Arizona Diamondbacks first baseman Paul Goldschmidt, with 189 hits.