Lee Marvin.
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Fred Lynn hit the first Grand Slam in an All-Star Game in 1983, which was played at Comiskey Park on the 50th Anniversary of the first Home Run to be hit in an All-Star Game. That was hit by Babe Ruth and was also hit at Comiskey Park in 1933, the first All-Star Game in history.
No. Through the 2010 All Star Game, there have been 175 home runs hit by 133 different players but none by a pitcher.
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Fred Lynn 1983 / Comiskey Park
last years all star game and the year before as well