Joe Montana of the San Francisco 49ers won the award three times (Super Bowls XVI, XIX and XXIV).
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he has two his first in superbowl 38 and his second in superbowl 39
It depends on what type of MVP you mean. If you mean the MVP of the league Tom Brady has two, one in 2007 and the second in 2010. If you mean Superbowl MVPs than he also has two, in in Superbowl XXXVI and Superbowl XXXVIII.
Joe Montana (3)
Gretzky
Wayne Gretzky (NHL) has the most regular season MVP titles with 9.