England was the first country to play soccer(football) because the sport was created there.
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The name of the first Austrailian soccer player to play for Liverpool was Craig Johnson
As it is a very popular sport all countries in the world play soccer.
There really is no first female individual who played professional soccer. However, the very first female league for soccer was the British Ladies Football Club.
Barcelona is a soccer club in Spain, but technically they do not paly "for" Spain, they just play in Spain.
Jahad Alihen Ahmad