John Smoltz is one of them. Jim "Catfish" Hunter was another.
Hundreds of players have worn this number, including Bobby Abreu, Felipe Alou, Adrian Beltre, Rod Carew, Mickey Lolich, Fred McGriff, Satchel Paige, Ken Singleton, and Mel Amada.
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Ted Williams wore the number 9 for the Boston Red Sox.
Steve Rodriguez Rico wore no. 6. Steve Rodriguez is right. Here's a list of who wore every number: http://www.redsoxdiehard.com/players/unifnums.html
Tony Perez wore #5 for the Boston Red Sox.
Ted Williams wore #9 for the Boston Red Sox and that number has since been retired by the team.
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