Yes ... both Chuck Essegian of the Los Angeles Dodgers and Bernie Carbo of the Boston Red Sox hit two pinch home runs in a World Series. Essegian's came in the 1959 WS (7th inning of Game 2 and 9th inning of Game 6) and Carbo's came in the 1975 WS (7th inning of Game 3 and 8th inning of Game 6).
Raul Ibanez of the New York Yankees hit two pinch home runs in the 2012 ALDS.
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Yes, David Freese of the St. Louis Cardinals accomplished that feat during the 2011 postseason. He hit two pinch-hit home runs in Game 4 of the National League Championship Series (NLCS) against the Milwaukee Brewers.
Through 2011, Alex Rodriguez has 13 postseason home runs in 16 series.
Bernie Williams hit the most career postseason home runs as a Yankee with 22.
Barry Bonds hit the most postseason home runs in a single season with 8 in 2002.
Angels
Yogi Berra hit the first pinch-hit home run in World Series history, off Brooklyn Dodgers pitcher Ralph Branca in Game 3 of the 1947 World Series.