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He may have appeared in ads for Baseball equipment , like the popularily circulated (Mantle and Mays) bat and ball sets. Sporting goods were not banned in comics advertising, though I doubt a direct Superman Tie- in. On the other hand there was a Superman-Muhammad Ali team- up in I believe the ( Brave and Bold) a comic book that speciallized in Team-ups of usually two characters who normally did not work together.

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Q: Was Mickey Mantle ever in a Superman comic?
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