They have never won it.
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This (2010) is the first time Serbia has been to the World Cup on her own - in 2006 it was Serbia & Montenegro, and in 1998 it was known as Yugoslavia.
Slovenia reached the World Cup finals in 2002. They will also be participating in 2010.
Algeria 0-1 Slovenia
the second round
Niki Lauda won the World cup 3 times.