Yes they do! They work great and are perfect for snap shooting and the like, however it is reccomended to Chrony no higher than 220 FPS. They are heavier than regular paintballs and they do not break open so there is a lot more energy when they hit the target.
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Paintballs will hurt more. They travel only slightly slower than air soft pellets, but have nearly ten times the mass. This gives it more foot-pounds of energy, causing more pain.
Never shoot someone with a pellet gun. Pellets will break skin easily. however Airsoft pellets hurt much less then paintballs.