There is no way to reduce fat from any one area of the body alone. This type of "Spot Reduction" is a myth. Your body loses fat from all areas of the body equally.
Doing arm exercises will firm and tone up the muscle under the fat, but has no direct effect on the fat itself.
General weight loss is the ONLY way to lose weight from any area of the body.
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Your body loses fat in different parts of your body based off of your genetic make-up. This means that if your body is prone to put fat on the arms first and lose it from the arms last, this is the way it will always lose fat. This is why some people put fat on their stomach whereas some people put fat on their hips and thighs. You cannot make your body burn fat from a specific area. Exercise and general weight-loss measures will eventually cause fat to leave your arms, even if it takes a while and you lose fat from other places first.
You can do arm exercises in the mean time, which will make your arms look more toned.