The word picadored is an adjective form of "picador" that is not a formal English word. It may be used to mean someone or something very angry.
As part of a bullfight, a bull is further enraged by having sharp lances jabbed into its neck by one or more picadores. In this case picadored would refer to a bull so enraged. (The purpose in bullfighting is to keep the bull's head low when he is being fought by the matador.)
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