It's two completely different conferences. The Big Ten contains the following teams: Ohio State, Michigan, Michigan State, Penn State, Iowa, Illinois, Indiana, Purdue, Wisconsin, and Minnesota. The Big 12 contains the following teams: Texas, Oklahoma, Oklahoma State, Nebraska, Kansas, Kansas State, Missouri, Texas A&M, Texas Tech, Baylor, Colorado, and Iowa State.
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The conference called the Big 12 is the old Big 8 conference that added 4 teams from the Southwest Conference. The conference called the Big 10 is the same one it used to be, but now actually has 11 members since the addition of Penn State.