Art has many cards that'll easily sell for over $100, but unfortunately, this isn't one of them.
You'd be lucky if you got more than 20 cents for it.
Hope that helps,
brian
www.artmonkfanatics.com
http://www.fantabular.net/art_monk(moved).htm
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A 1991 Topps Rickey Henderson All Star card number 391 has a book value of about .15 cents in near/mint -mint condition. Professionally graded cards will sell for more money than a non-graded card in the same condition. Condition is important.
Common flaws with Baseball cards include: rounded edges, creases, off centered, and faded color. Any or all flaws will devalue the card significantly.