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When a company like PSA/DNA authenticates a signature they use sample of the player's signature to compare with, and analyze. A College ball player would most likely be on file, and would most likely not be able to be authenticated, unless at a later date the ball player makes it to the big Leagues. The only other option would be to have it signed in the presence of, and authenticated in person.

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Q: How do you get a coa on a college autograph?
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