No.
Schilling came close in 2007 when he no hit the Oakland Athletics for 8 2/3 innings. Shannon Stewart of the A's singled to right field to end the no hit bid.
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Yes, on March 28th, 2003 for Liberty High School. And another on his next start on April 4th.
He threw a 4-Seam and a 2-Seam fastball as well as a Slider, Splitter, and occasional Changeup