There is no such thing as blocking with chi, but you can improve your chi flow making your blocks and strikes more powerful.
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Yes, Tai Chi Chuan is a Chinese Martial Art.
Tai Chi is a very ancient martial art that has been used in China for thousands of years.
Tai Chi
They are words for the "life force", the energy in the universe and in all things. Martial arts teach how to feel and use the power of this force."Chi" is the Chinese name for this energy and "Ki" is the Japanese word for it.For examples: The word chi is used in the martial art Tai Chi and ki is a part of the word Reiki which is Japanese for universal life force that is used in the practice of Reiki, an energy healing discipline.See the related questions for more information.
Most people think tai chi, aka tai chi quan