If you look at every good centre-back the majority of them have a world class partner in defence, for example: John Terry (and Ricardo Carvalho) , Lucio ( and Samuel/Materazzi, Puyol (Pique), Vidic ( Rio Ferdinand) , Mertesacker (Naldo) , Mexes (Juan)
Also, as a general rule one of the two centre-backs will be siginifcantly taller/heavier than the other. Height means that the defender can have an advantage in the air, weight is good for muscling out the opposition.
Some tall centre-backs are: Naldo, Luisao, Fazio, Westermann, Sebastian Prodl, Garay, Bruno Alves and Skrtel.
Some heavy centre-backs are: Terry, Materazzi, Van Buyten, Mertesacker, Kompany and Richard Dunne.
It's peoples opinions
John Terry voted best in Europe 2009 in Champions League.
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The best right back in the world according to me is the Real Madrid right back Sergio Ramos.
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The one we want to establish
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Puyol
In the whole history of the club is Alessandro Del Piero,the legend of the Juventus.For now is Giorgio Chielini,he is so amazing in the defense no one can pass him when he has a big game...i think is the best center back in the world combined with Pique of Barcelona.